The Battle of Brienne (29 January 1814) saw an Imperial French army led by Emperor Napoleon attack Prussian and Russian forces commanded by Prussian Field Marshal Gebhard Leberecht von Blcher. After heavy fighting that went on into the night, the French seized the chteau, nearly capturing Blcher. However, the French were unable to dislodge the Russians from the town of Brienne-le-Chteau. Napoleon himself, making his first appearance on a battlefield in 1814, was also nearly captured. Very early the next morning, Blcher's troops quietly abandoned the town and retreated to the south, conceding the field to the French.

In late December 1813, two Allied armies initially numbering 300,000 men smashed through France's weak defenses and moved west. By late January, Napoleon personally took the field to lead his armies. The French emperor hoped to cripple Blcher's army before it could combine with the main Allied army under Austrian Field Marshal Karl Philipp, Prince of Schwarzenberg. Napoleon's gamble failed and Blcher escaped to join Schwarzenberg. Three days later, the two Allied armies combined their 120,000 men and attacked Napoleon in the Battle of La Rothire.

In the War of the Sixth Coalition (March 1813 – May 1814), sometimes known in Germany as the Wars of Liberation, a coalition of Austria, Prussia, Russia, the United Kingdom, Portugal, Sweden, Spain and a number of German States defeated France and drove Napoleon into exile on Elba. After the disastrous French invasion of Russia of 1812 in which they had been forced to support France, Prussia and Austria joined Russia, the United Kingdom, Sweden, Portugal and the rebels in Spain who were already at war with France.

The War of the Sixth Coalition saw major battles at Lützen, Bautzen, and Dresden. The even larger Battle of Leipzig (also known as the Battle of Nations) was the largest battle in European history before World War I. Ultimately, Napoleon's earlier setbacks in Portugal, Spain, and Russia proved to be the seeds of his undoing. With their armies reorganized, the allies drove Napoleon out of Germany in 1813 and invaded France in 1814. The Allies defeated the remaining French armies, occupied Paris, and forced Napoleon to abdicate and go into exile. The French monarchy was revived by the allies, who handed rule to the heir of the House of Bourbon in the Bourbon Restoration.

The "Hundred Days" War of the Seventh Coalition was triggered in 1815 when Napoleon escaped from his captivity on Elba and returned to power in France. He was defeated again for the final time at Waterloo, ending the Napoleonic Wars.